By Karen I. Goldberg and Alan S. Goldman (Eds.)
Content material: 1. Organometallic C-H bond activation : an creation / Alan S. Goldman and Karen I. Goldberg -- 2. C-H bond activation by means of iridium and rhodium complexes : catalytic hydrogen-deuterium trade and C-C bond-forming reactions / Steven R. Klei, Kian L. Tan, Jeffrey T. Golden, Cathleen M. Yung, Reema ok. Thalji, Kateri A. Ahrendt, Jonathan A. Ellman, T. Don Tilley and Robert G. Bergman
Read or Download Activation and Functionalization of C—H Bonds PDF
Similar organic books
This booklet is a set of studies at the renal delivery of natural elements. the 1st chapters take care of normal features of the subject. the next articles deal with the current wisdom at the renal trans port of particular compounds or periods of natural ingredients, while the fmal bankruptcy on comparative body structure bargains with the renal trans port of natural elements in non-mammalian vertebrates.
Approximately 8 years in the past, the catalytic carbonylation of natural nitro compounds used to be a examine box constructed sufficient to justify a slightly lengthy evaluation in this topic. Now, we think that the medical effects and new achievements during this box, extremely important even from an commercial perspective, require a ebook as a way to be properly offered.
Extra info for Activation and Functionalization of C—H Bonds
Chem. Soc. 2002, 124, 10605. 66. Halpern, J. Inorg. Chim. Acta. 1985,100,41. 67. Rest, A. ;Graham, W. A. ; Hoyano, J. ; McMaster, A. D. J. ,Chem. Commun. 1984, 624. 68. ; Hoffmann, R. J. Am. Chem. Soc. 1984, 106, 2006. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2004. ch001 109, 69. Wenzel, T. ; Bergman, R. G. J. Am. Chem. Soc. 1986,108,4856. 70. Nolan, S. ; Hoff, C. ; Stoutland, P. ; Newman, L. ; Buchanan, J. ; Bergman, R. ; Yang, G. ; Peters, K. S. J. Am. Chem. Soc. 1987, 3143.
But the boryl group is not merely acting as a "trap" for a C - H bond after the task of activation is accomplished by the transition metal center. Rather, the empty p-orbital of a metalated boryl group plays an intimate role in. promoting the activation process. Indeed, the development of this catalysis was based upon the observation that CpM(CO) (boryl) complexes showed stoichiometric reactivity towards alkanes, unlike their counterparts CpM(CO) R (R = alkyl, aryl or H) (138,139). ) n n Organometallic C-H Activation Modes Other than Oxidative Addition and Electrophilic The modes of C - H bond activation discussed in the present section have been the subject of extensive research, although not on the scale seen for oxidative addition and electrophilic addition.
Smith, M . ,IIIJ. Am. Chem. Soc. 1999, 121, 7696. 138. Waltz, Κ. ; Hartwig, J. F. Science 1997, 277, 211. 139. Webster, C. ; Hall, M . ; Hartwig, J. F. J. Am. Chem. Soc. 2003, 125, 858. 140. Thompson, M . ; Baxter, S. ; Bulls, A. ; Burger, B. ; Nolan, M . ; Santarsiero, B. ; Schaefer, W. ; Bercaw, J. E. J. Am. Chem. Soc. 1987, 109, 203. 141. Watson, P. L. J. Am. Chem. Soc. 1983, 105, 6491. 142. Watson, P. ; Parshall, G. W. Acc. Chem. Res. 1985, 18, 51. 143. (a) Jordan, R. ; Taylor, D. F. J. Am.