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By Guangbin Dong

The sequence subject matters in present Chemistry offers severe studies of the current and destiny tendencies in sleek chemical study. The scope of insurance is all parts of chemical technological know-how together with the interfaces with similar disciplines reminiscent of biology, drugs and fabrics technological know-how. The aim of every thematic quantity is to provide the non-specialist reader, even if in academia or undefined, a accomplished perception into a space the place new learn is rising that is of curiosity to a bigger medical viewers. every one assessment in the quantity significantly surveys one point of that subject and locations it in the context of the quantity as a complete. the main major advancements of the final five to ten years are awarded utilizing chosen examples to demonstrate the foundations mentioned. The insurance isn't meant to be an exhaustive precis of the sphere or comprise huge amounts of knowledge, yet may still otherwise be conceptual, targeting the methodological considering that would let the non-specialist reader to appreciate the data awarded. Contributions additionally supply an outlook on capability destiny advancements within the box. overview articles for the person volumes are invited via the quantity editors. Readership: examine chemists at universities or in undefined, graduate students

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The overall scheme shows that the rate-determining step of the intramolecular arylcyanation is either the exchange of bound phosphorus by the tethered alkene or the migratory insertion step rather than oxidative addition of Ar–CN bond. 4 Summary, Conclusions, Outlook Synthetic reactions involving C–CN activation by metal catalysis are reviewed in this chapter. All the transformations presented herein provide the synthetic community with novel reaction modes of nitriles, and thus with new ideas and strategies for the syntheses of target molecules.

Wen Q, Jin J, Mei Y, Lu P, Wang Y (2013) Eur J Org Chem 4032 65. Jiang Z, Huang Q, Chen S, Long L, Zhou X (2012) Adv Synth Catal 354:589 66. Li J-H, Song R-J, Wu J-C, Liu Y, Deng G-B, Wu C-Y, Wei W-T (2012) Synlett 23:2491 58 Y. Nakao 67. Jin J, Wen Q, Lu P, Wang Y (2012) Chem Commun 48:9933 68. Yuen OY, Choy PY, Chow WK, Wong WT, Kwong FY (2013) J Org Chem 78:3374 69. Wen Q, Jin J, Hu B, Lu P, Wang Y (2012) RSC Adv 2:6167 70. Zheng S, Yu C, Shen Z (2012) Org Lett 14:3644 71. Luo FH, Chu CI, Cheng CH (1998) Organometallics 17:1025 72.

Intramolecular arylcyanation of simple alkenes proceeds smoothly by cooperative nickel/Lewis acid catalysis (Schemes 37, 38, and 39) [102–104], whereas palladium catalysts have been shown to be useful for intramolecular 54 Y. Nakao Scheme 38 Total synthesis of (–)-esermethole through enantioselecive intramolecular arylcyanation of alkenes Scheme 39 Formal total synthesis of (–)-eptazocine through enantioselecive intramolecular arylcyanation of alkenes Scheme 40 Enantioselective intramolecular cyanocarbamoylation of alkenes catalyzed by palladium cyanocarbamoylation (Scheme 40) [105–109].

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